[HTML payload içeriği buraya]
26.6 C
Jakarta
Tuesday, April 28, 2026

Chemical hardness engineering synchronizes crystallization in perovskite tandems


  • He, R. et al. Large-bandgap organic-inorganic hybrid and all-inorganic perovskite photo voltaic cells and their utility in all-perovskite tandem photo voltaic cells. Vitality Environ. Sci. 14, 5723–5759 (2021).

    Article 
    CAS 

    Google Scholar
     

  • He, R. et al. Bettering interface high quality for 1-cm2 all-perovskite tandem photo voltaic cells. Nature 618, 80–86 (2023).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Li, L. et al. Versatile all-perovskite tandem photo voltaic cells approaching 25% effectivity with molecule-bridged hole-selective contact. Nat. Vitality 7, 708–717 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Wang, Y. et al. Homogenized contact in all-perovskite tandems utilizing tailor-made 2D perovskite. Nature 635, 867–873 (2024).

    Article 
    PubMed 

    Google Scholar
     

  • Ge, Y. et al. Suppressing wide-angle mild loss and non-radiative recombination for environment friendly perovskite photo voltaic cells. Nat. Photon. 19, 170–177 (2025).

    Article 
    CAS 

    Google Scholar
     

  • Li, M. et al. In situ coating technique for versatile all-perovskite tandem modules. Nat. Photon. 19, 1255–1263 (2025).

    Article 
    CAS 

    Google Scholar
     

  • Zhou, J. et al. Blended tin-lead perovskites with balanced crystallization and oxidation barrier for all-perovskite tandem photo voltaic cells. Nat. Commun. 15, 2324 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Yang, X. et al. Understanding and manipulating the crystallization of Sn–Pb perovskites for environment friendly all-perovskite tandem photo voltaic cells. Nat. Photon. 19, 426–433 (2025).

    Article 
    CAS 

    Google Scholar
     

  • Zhu, J. et al. Customized-tailored gap transport layer utilizing oxalic acid for high-quality tin-lead perovskites and environment friendly all-perovskite tandems. Sci. Adv. 10, eadl2063 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Lin, R. et al. All-perovskite tandem photo voltaic cells with dipolar passivation. Nature 648, 600–606 (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Duan, C. et al. Scalable fabrication of wide-bandgap perovskites utilizing inexperienced solvents for tandem photo voltaic cells. Nat. Vitality 10, 318–328 (2024).

    Article 

    Google Scholar
     

  • Hu, S. et al. Optimized service extraction at interfaces for 23.6% environment friendly tin–lead perovskite photo voltaic cells. Vitality Environ. Sci. 15, 2096–2107 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Pearson, R. G. Exhausting and smooth acids and bases, HSAB, half I: elementary ideas. J. Chem. Educ. 45, 581–584 (1968).

  • Parr, R. G. & Pearson, R. G. Absolute hardness: companion parameter to absolute electronegativity. J. Am. Chem. Soc. 105, 7512–7516 (1983).

    Article 
    CAS 

    Google Scholar
     

  • Huang, T. et al. Efficiency-limiting formation dynamics in mixed-halide perovskites. Sci. Adv. 7, eabj1799 (2021).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Wang, R. et al. Environment friendly wide-bandgap perovskite photovoltaics with homogeneous halogen-phase distribution. Nat. Commun. 15, 8899 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Zhang, Y. et al. Synchronized crystallization in tin-lead perovskite photo voltaic cells. Nat. Commun. 15, 6887 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Li, C. et al. Diamine chelates for elevated stability in blended Sn–Pb and all-perovskite tandem photo voltaic cells. Nat. Vitality 9, 1388–1396 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Liang, C. et al. Two-dimensional Ruddlesden-Popper layered perovskite photo voltaic cells primarily based on phase-pure skinny movies. Nat. Vitality 6, 38–45 (2021).

    Article 

    Google Scholar
     

  • Liang, Z. et al. Homogenizing out-of-plane cation composition in perovskite photo voltaic cells. Nature 624, 557–563 (2023).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Jung, H. S., Han, G. S., Park, N. G. & Ko, M. J. Versatile perovskite photo voltaic cells. Joule 3, 1850–1880 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Amoroso, D. et al. The central position of colloids to elucidate the crystallization dynamics of halide perovskites: a essential evaluation. Matter 7, 2399–2430 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Fonseca, A. F. V. et al. In situ PL monitoring of halide trade at 3D/QD heterojunction perovskite photo voltaic cells. ACS Vitality Lett. 9, 3177–3186 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Tian, R., Zhou, S., Meng, Y., Liu, C. & Ge, Z. Materials and system design of versatile perovskite photo voltaic cells for next-generation energy provides. Adv. Mater. 36, 2311473 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Qin, M., Chan, P. F. & Lu, X. A scientific evaluation of metallic halide perovskite crystallization and movie formation mechanism unveiled by in situ GIWAXS. Adv. Mater. 33, 2105290 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Chen, Y. et al. Nuclei engineering for even halide distribution in secure perovskite/silicon tandem photo voltaic cells. Science 385, 554–560 (2024).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Exarhos, S., Palmes, E. & Mangolini, L. Structural homogenization and cation ordering in CZTS movies throughout sulfurization as probed by way of in-situ Raman. Skinny Stable Movies 684, 21–30 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Ho, H. P., Harrison, I., Baba-Ali, N. & Tuck, B. Diffusion-induced defects in GaAs by zinc and the results of post-diffusion anneal. J. Appl. Phys. 69, 3494–3502 (1991).

    Article 
    CAS 

    Google Scholar
     

  • Abdi-Jalebi, M. et al. Maximizing and stabilizing luminescence from halide perovskites with potassium passivation. Nature 555, 497–501 (2018).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Bischak, C. G. et al. Origin of reversible photoinduced part separation in hybrid perovskites. Nano Lett. 17, 1028–1033 (2017).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhang, Z. et al. Suppression of part segregation in wide-bandgap perovskites with thiocyanate ions for perovskite/natural tandems with 25.06% effectivity. Nat. Vitality 9, 592–601 (2024).

    Article 
    CAS 

    Google Scholar
     

  • DuBose, J. T. & Kamat, P. V. Gap trapping in halide perovskites induces part segregation. Acc. Mater. Res. 3, 761–771 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Tao, J. L. et al. F-type pseudo-halide anions for high-efficiency and secure wide-band-gap inverted perovskite photo voltaic cells with fill issue exceeding 84%. ACS Nano 16, 10798–10810 (2022).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Track, Y.-H. et al. Planar defect–free pure purple perovskite light-emitting diodes by way of metastable part crystallization. Sci. Adv. 8, eabq2321 (2022).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Ren, A. et al. Environment friendly perovskite photo voltaic modules with minimized nonradiative recombination and native service transport losses. Joule 4, 1263–1277 (2020).

    Article 
    CAS 

    Google Scholar
     

  • Peng, W. et al. Lowering nonradiative recombination in perovskite photo voltaic cells with a porous insulator contact. Science 379, 683–690 (2023).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Pan, Y. et al. Floor chemical sharpening and passivation decrease non-radiative recombination for all-perovskite tandem photo voltaic cells. Nat. Commun. 15, 7335–7335 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Pauling, L. The Nature of the Chemical Bond third edn (Cornell Univ. Press, 1960).

  • Becke, A. D. Density-functional thermochemistry. III. The position of tangible trade. J. Chem. Phys. 98, 5648–5652 (1993).

    Article 
    CAS 

    Google Scholar
     

  • Becke, A. D. Density-functional exchange-energy approximation with right asymptotic conduct. Phys. Rev. A 38, 3098–3100 (1988).

    Article 
    CAS 

    Google Scholar
     

  • Lee, C., Yang, W. & Parr, R. G. Growth of the Colle-Salvetti correlation-energy components right into a purposeful of the electron density. Phys. Rev. B 37, 785–789 (1988).

    Article 
    CAS 

    Google Scholar
     

  • Petersson, G. A. & Al-Laham, M. A. A whole foundation set mannequin chemistry. II. Open-shell methods and the entire energies of the first-row atoms. J. Chem. Phys. 94, 6081–6090 (1991).

    Article 
    CAS 

    Google Scholar
     

  • Petersson, G. A. et al. A whole foundation set mannequin chemistry. I. The entire energies of closed-shell atoms and hydrides of the first-row parts. J. Chem. Phys. 89, 2193–2218 (1988).

    Article 
    CAS 

    Google Scholar
     

  • Lu, T. & Chen, F. Multiwfn: a multifunctional wavefunction analyzer. J. Comput. Chem. 33, 580–592 (2012).

    Article 
    PubMed 

    Google Scholar
     

  • Kresse, G. & Furthmüller, J. Environment friendly iterative schemes for ab initio total-energy calculations utilizing a plane-wave foundation set. Phys. Rev. B 54, 11169–11186 (1996).

    Article 
    CAS 

    Google Scholar
     

  • Perdew, J. P., Burke, Okay. & Ernzerhof, M. Generalized gradient approximation made easy. Phys. Rev. Lett. 77, 3865–3868 (1996).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Blöchl, P. E. Projector augmented-wave methodology. Phys. Rev. B 50, 17953–17979 (1994).

    Article 

    Google Scholar
     

  • Grimme, S., Antony, J., Ehrlich, S. & Krieg, H. A constant and correct ab initio parametrization of density purposeful dispersion correction (DFT-D) for the 94 parts H-Pu. J. Chem. Phys. 132, 154104 (2010).

    Article 
    PubMed 

    Google Scholar
     

  • Grimme, S., Ehrlich, S. & Goerigk, L. Impact of the damping operate in dispersion corrected density purposeful idea. J. Comput. Chem. 32, 1456–1465 (2011).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Related Articles

    LEAVE A REPLY

    Please enter your comment!
    Please enter your name here

    Latest Articles