Xie, C. L. et al. Tandem catalysis for CO2 hydrogenation to C2-C4 hydrocarbons. Nano Lett. 17, 3798–3802 (2017).
Lewis, R. J. et al. Extremely environment friendly catalytic manufacturing of oximes from ketones utilizing in situ-generated H2O2. Science 376, 615–620 (2022).
Yang, T. et al. Ultrahigh-strength and ductile superlattice alloys with nanoscale disordered interfaces. Science 369, 427–432 (2020).
Shi, P. J. et al. Hierarchical crack buffering triples ductility in eutectic herringbone high-entropy alloys. Science 373, 912–918 (2021).
He, Q. F. et al. A extremely distorted ultraelastic chemically advanced Elinvar alloy. Nature 602, 251–257 (2022).
Oh, N. R. et al. Double-heterojunction nanorod light-responsive LEDs for show purposes. Science 355, 616–619 (2017).
Ibrar, M. & Skrabalak, S. E. Designer plasmonic nanostructures for unclonable anticounterfeit tags. Small Struct. 2, 2100043 (2021).
Jiang, B. B. et al. Excessive-entropy-stabilized chalcogenides with excessive thermoelectric efficiency. Science 371, 830–834 (2021).
Jiang, B. B. et al. Excessive figure-of-merit and energy technology in high-entropy GeTe-based thermoelectrics. Science 377, 208–213 (2022).
Pendharkar, M. et al. Parity-preserving and magnetic field-resilient superconductivity in InSb nanowires with Sn shells. Science 372, 508–511 (2021).
Okamoto, H., Schlesinger, M. E. & Mueller, E. M. (eds) Binary Alloy Section Diagrams (ASM Worldwide, 2016).
Loffler, T. et al. Discovery of a multinary noble metal-free oxygen discount catalyst. Adv. Power Mater. 8, 1802269 (2018).
Kusada, Ok. et al. Nonequilibrium flow-synthesis of solid-solution alloy nanoparticles: from immiscible binary to high-entropy alloys. J. Phys. Chem. C 125, 458–463 (2021).
Chen, Y. F. et al. Synthesis of monodisperse excessive entropy alloy nanocatalysts from core@shell nanoparticles. Nanoscale Horiz. 6, 231–237 (2021).
Wang, C. Y. et al. Side-dependent deposition of extremely strained alloyed shells on intermetallic nanoparticles for enhanced electrocatalysis. Nano Lett. 17, 5526–5532 (2017).
Chen, P. C. et al. Polyelemental nanoparticle libraries. Science 352, 1565–1569 (2016).
Chen, P. C. et al. Interface and heterostructure design in polyelemental nanoparticles. Science 363, 959–964 (2019).
Chen, P. C. et al. Chain-end functionalized polymers for the managed synthesis of sub-2 nm particles. J. Am. Chem. Soc. 142, 7350–7355 (2020).
Fenton, J. L., Steimle, B. C. & Schaak, R. E. Tunable intraparticle frameworks for creating advanced heterostructured nanoparticle libraries. Science 360, 513–517 (2018).
Steimle, B. C., Fenton, J. L. & Schaak, R. E. Rational development of a scalable heterostructured nanorod megalibrary. Science 367, 418–424 (2020).
Piccolo, L. et al. Understanding and controlling the construction and segregation behaviour of AuRh nanocatalysts. Sci. Rep. 6, 35226 (2016).
Chen, P.-C. et al. Chemical and structural evolution of AgCu catalysts in electrochemical CO2 discount. J. Am. Chem. Soc. 145, 10116–10125 (2023).
Wang, B. et al. Common synthesis of high-entropy alloy and ceramic nanoparticles in nanoseconds. Nat. Synth. 1, 138–146 (2022).
Yang, C. L. et al. Sulfur-anchoring synthesis of platinum intermetallic nanoparticle catalysts for gas cells. Science 374, 459–464 (2021).
Feng, G. et al. Sub-2 nm ultrasmall high-entropy alloy nanoparticles for very superior electrocatalytic hydrogen evolution. J. Am. Chem. Soc. 143, 17117–17127 (2021).
Buendia, F., Vargas, J. A., Johnston, R. L. & Beltran, M. R. Examine of the steadiness of small AuRh clusters discovered by a genetic algorithm methodology. Comput. Theor. Chem. 1119, 51–58 (2017).
Rahm, J. M. & Erhart, P. Understanding chemical ordering in bimetallic nanoparticles from atomic-scale simulations: the competitors between bulk, floor, and pressure. J. Phys. Chem. C 122, 28439–28445 (2018).
Christensen, A., Stoltze, P. & Norskov, J. Ok. Measurement dependence of phase-separation in small bimetallic clusters. J. Phys. Condens. Matter 7, 1047–1057 (1995).
Fevre, M., Le Bouar, Y. & Finel, A. Thermodynamics of phase-separating nanoalloys: single particles and particle assemblies. Phys. Rev. B 97, 195404 (2018).
Srivastava, C., Chithra, S., Malviya, Ok. D., Sinha, S. Ok. & Chattopadhyay, Ok. Measurement dependent microstructure for Ag-Ni nanoparticles. Acta Mater. 59, 6501–6509 (2011).
Kusada, Ok., Yamauchi, M., Kobayashi, H., Kitagawa, H. & Kubota, Y. Hydrogen-storage properties of solid-solution alloys of immiscible neighboring parts with Pd. J. Am. Chem. Soc. 132, 15896–15898 (2010).
Zhang, Q. et al. Selective management of fcc and hcp crystal buildings in Au-Ru solid-solution alloy nanoparticles. Nat. Commun. 9, 510 (2018).
Zhang, H., Wang, L., Lu, L. & Toshima, N. Preparation and catalytic exercise for cardio glucose oxidation of crown jewel structured Pt/Au bimetallic nanoclusters. Sci. Rep. 6, 30752 (2016).
Toshima, N. & Hirakawa, Ok. Polymer-protected bimetallic nanocluster catalysts having core/shell construction for accelerated electron switch in visible-light-induced hydrogen technology. Polym. J. 31, 1127–1132 (1999).
Toshima, N. & Yonezawa, T. Bimetallic nanoparticles-novel supplies for chemical and bodily purposes. New J. Chem. 22, 1179–1201 (1998).
Meischein, M. et al. Elemental (im-)miscibility determines section formation of multinary nanoparticles co-sputtered in ionic liquids. Nanoscale Adv. 4, 3855–3869 (2022).
Rajeeva, B. B. et al. Accumulation-driven unified spatiotemporal synthesis and structuring of immiscible metallic nanoalloys. Matter 1, 1606–1617 (2019).
Feng, J. C. et al. Unconventional alloys confined in nanoparticles: constructing blocks for brand spanking new matter. Matter 3, 1646–1663 (2020).
Qi, W. H. & Wang, M. P. Measurement impact on the cohesive power of nanoparticle. J. Mater. Sci. Lett. 21, 1743–1745 (2002).
Xiong, S. Y., Qi, W. H., Huang, B. Y. & Wang, M. P. Measurement-, shape- and composition-dependent alloying capacity of bimetallic nanoparticles. ChemPhysChem 12, 1317–1324 (2011).
Qi, W. H., Huang, B. Y. & Wang, M. P. Measurement and shape-dependent formation enthalpy of binary alloy nanoparticles. Phys. B 404, 1761–1765 (2009).
Sneed, B. T., Younger, A. P. & Tsung, C. Ok. Increase pressure in colloidal metallic nanoparticle catalysts. Nanoscale 7, 12248–12265 (2015).
Ferrando, R. Construction and Properties of Nanoalloys (Elsevier, 2016).
Chen, P. C. et al. Revealing the section separation habits of thermodynamically immiscible parts in a nanoparticle. Nano Lett. 21, 6684–6689 (2021).
Sohlberg, Ok., Pennycook, T. J., Zhou, W. & Pennycook, S. J. Insights into the bodily chemistry of supplies from advances in HAADF-STEM. Phys. Chem. Chem. Phys. 17, 3982–4006 (2015).
Vanzan, M., Jones, R. M., Corni, S., D’Agosta, R. & Baletto, F. Exploring AuRh nanoalloys: a computational perspective on the formation and bodily properties. ChemPhysChem 23, e202200035 (2022).
Valizadeh, Z. & Abbaspour, M. Floor power, relative stability, and structural properties of Au-Pt, Au-Rh, Au-Cu, and Au-Pd nanoclusters created in inert-gas condensation course of utilizing MD simulation. J. Phys. Chem. Solids 144, 109480 (2020).
Koch, C. T. Willpower of Core Construction Periodicity and Level Defect Density alongside Dislocations. PhD thesis, Arizona State Univ. (2002).
Kresse, G. & Furthmuller, J. Environment friendly iterative schemes for ab initio total-energy calculations utilizing a plane-wave foundation set. Phys. Rev. B 54, 11169–11186 (1996).
Kresse, G. & Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave methodology. Phys. Rev. B 59, 1758–1775 (1999).
Perdew, J. P., Burke, Ok. & Ernzerhof, M. Generalized gradient approximation made easy. Phys. Rev. Lett. 77, 3865–3868 (1996).