Rising InN content material in InxGa1-xN compound is paramount for optoelectronic functions, and has been demonstrated in homogeneous nanowires or intentionally grown nanowire heterostructures. Right here, we exhibit spontaneous core-shell InxGa1-xN nanowires grown by molecular beam epitaxy on Si substrates at 625 oC. These heterostructures have a excessive InN fraction within the cores round 0.4, sharp interfaces and exhibit brilliant photoluminescence at 650 nm. The stunning impact of fabric separation is attributed to the periodically altering atmosphere for instantaneous development of single monolayers on prime of nanowires. As a result of a smaller assortment size of N adatoms, every monolayer nucleates underneath a balanced V/III ratio, however then continues underneath extremely group III wealthy situations. Consequently, the miscibility hole is suppressed within the cores however stays within the shells. These outcomes present a easy methodology for acquiring high-quality InGaN heterostructures emitting within the prolonged wavelength vary.